Metallurgical Thermodynamics & Kinetics Notes VSSUT – MTK Notes VSSUT of Total Complete Notes
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Link: Complete Notes
Module – 1
Introduction to Thermodynamics,Thermodynamics,Process ,
Property,Equation of States ,Simple Equilibrium,Thermodynamic Equilibrium,
PHASE DIAGRAM / CONSTITUTION DIAGRAM,Phase Diagram of One-component System,
Internal Energy,Phase Diagram ,Gibbs Phase Rule .
Link: Module – 1
Module – 2
First Law of Thermodynamics, First Law of Thermodynamics , Heat Capacity ,
Enthalpy,Hess’s Law,Kirchhoff’s Law ,Thermos Chemistry & its Applications,Adiabatic Process,
Reversible Isothermal Process,Adiabatic & Isothermal Process.
Link: Module – 2
Module – 3
Second Law of Thermodynamics,Second Law of Thermodynamics ,
Entropy, Entropy of a Perfect Gas ,Temperature Dependence of Entropy ,
Some Alternative Statement, Spontaneous Process,Reversible & Irreversible Process.
Link: Module – 3
Module – 4
Auxiliary Functions & Relations, Criteria for Equilibria,
Free Energy,Combined Expressions of First & Second Law of Thermodynamics ,
Criteria of Thermodynamic Equilibria,Gibbs Helmholtz Equation ,
Maxwell’s Relation,Transformation Formula .
Link: Module – 4
Module – 5
Third Law of Thermodynamics, Statistical Thermodynamics,hird Law of Thermodynamics ,
Statistical Thermodynamics, Postulates of Statistical Thermodynamics ,
Stalin Formula, Relationship between Statistical Interpretations of Entropy,
Debye & Einstein Concept of Heat Capacity.
Link: Module – 5
Module – 6
Fugacity,Escaping Tendency , Fugacity,Arrhenius Equation ,
Activity,Equilibrium Constant , Use of S Function ,
Ellingham-Richardson Diagram.
Link: Module – 6
Module – 7
Thermodynamics of Solutions, Ideal & Non-Ideal Solutions ,
Partial & Integral Molar Quantities,Gibbs-Duhem Equation,Activity vs Mole Fraction (Henry’s Law) ,
Regular Solutions,Quasi-Chemical Approach to Solutions ,Sievert’s Law,
One Weight Percent Standard State, Chemical Potential ,
Free Energy Diagram for Binary Alloys Systems,Experimental Determination of Phase Diagrams ,
Clapeyron Equation.
Link: Module – 7
Module – 8
Topochemical Reaction,Topochemical Reaction , Johnson-Mehl’s Equation ,
Types of Reaction, Reaction of Lumps , Important Notes ,
Difference between Molecularity & Order of the Reaction.
Link: Module – 8
Module – 9
Electrometallurgy,Thermodynamics of Electrometallurgy Cells ,
Thermodynamics of Reversible Galvanic Cells, Relation between Cell EMF (E) & Free Energy of Cell Reaction (????G) .
Link: Module – 9
Module – 10
Miscellaneous,Phase Stability Diagrams ,Defects in Thermodynamics ,
Thermal Analysis,Homogeneous & Heterogeneous Equilibria ,
Controlled Atmosphere (CA).
